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Two hours, according to my favorite authority on such matters: www.stilltasty.com/
That's their recommendation for fresh cooked broccoli, but I don't see any reason why it would be different for frozen once it's been cooked.
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Two hours, according to my favorite authority on such matters: www.stilltasty.com/
That's their recommendation for fresh cooked broccoli, but I don't see any reason why it would be different for frozen once it's been cooked.