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To get raisins to plump back up, you have to heat them or have them soak in boiling water. If it is only the flavour of the rum you want to add, then I would boil up a 1/2 cup and add the raisins for a 20-minute soak. If you want the "punch" of rum added to the raisins, you could try warming the rum gently, but not boiling, and adding the raisins for a day-long soak.
