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I've seen some at Surfas and Whole Foods and I bought a bag (Bob's Mills, is it called?) in the organic section at a Ralph's but it was a long time ago.
I'd suggest you also try a Jons supermarket in their "international foods" section. The one either on Hobart & Santa Monica or on Vermont would be likely to have it.
You should call Surfas ahead if you go because sometimes they're out of some of the flours.If you find some, it can keep superbly in the freezer for a very long time. It doesn't freeze, so no need to thaw.
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Surfas carries buckwheat flour, with all the flours in the cold case. They handle their grains with great care/great quality. I know it's a bit of a drive from Los Feliz, but worth it.
I have also bought buckwheat flour at Japanese markets ( for soba !), Mitsuwa has it for sure. So you could check the markets near you, I guess Little Tokyo. -
I just went on a massive search for buckwheat flour, and the only place I was able to find it was also Whole Foods. If you're anti-WF, there's a store on Magnolia in Burbank called Food for Life that I was going to try, but they were closed when I drove by so I can't confirm. They do have all natural, organic, whole grain stuff galore, though.
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I have found this in Whole Foods before, though not all. I think I also found it in bulk bins at Rainbow Acres. Marina Farms on Centinela, near Jefferson also used to have it. Sorry, I don't live close to you, so have no nearby locations for you. Whole Foods have always been very helpful on the phone with inventory check and price checks. They even held an item for me, when it was the last of it's kind on the shelf. So I highly recommend calling your local WF.