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Z Tejas in downtown Tempe has a decent brunch on Saturdays and Sundays with some southwestern-influenced breakfast items. If you like Bloody Marys, the $3 Bloody Mary bar (with any kind of vodka you want) is great.
Four Peaks also has brunch on Sundays.
The US Egg on Baseline near Mill is pretty decent standard breakfast fare.
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Us Egg
131 E Baseline Rd, Tempe, AZ 85283Four Peaks Brewing Co
1340 E 8th St, Tempe, AZ 85281Z Tejas Grill
20 W 6th St, Tempe, AZ 85281 -
Harlow's on University
Cracker & Co Cafe on Priest and Elliot
http://www.crackersandcompanycafe.com/Wildflower Bread Company at Guadalupe and McClintock
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Harlow's Cafe
1021 W University Dr, Tempe, AZ 85281Wildflower Bread Co
6428 S McClintock Dr, Tempe, AZ 85283