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I always think Tea Adore would be a great first date place. Its a little French tea place on 13th between fifth and University. They do not have alchohal but the space (upstairs) has a cute causual county atmosphere. they have good simple soups and sandwiches and if its not crowded you can linger for a long time. But they do close at 6.
I did go on a first date once at Mud Hut on East 9th. Also mellow, a bit hipster, but good coffee, food and they searce funky beers.
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Cafe Angelique on Grove would be perfect, I think. Good coffee and interesting tea selection. I haven't had their food, but the pastries always look great and they also have a menu with soups, sandwiches, salads and the like. As suggested above, Ameteller is nice as well, but service can be a little spotty.
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