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You might try either Tosca (http://www.toscadc.com/) at 1112 F St. or 701 Restaurant (http://www.701restaurant.com/) at 701 Penn Ave.
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Capital Grille? Steakhouse on Penn Ave. on 6th and Penn.
http://www.capitalgrille.com/Location...
There are a multiple of other dining options in that area, but are probably not good for business dinners due to the extreme volume of conversations. Ruth's Chris is also nearby on 9th and H. I recommended steakhouses b/c they're generally more hush hush in the dining area. Both are a short walk from the hotel.