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I think Albertsons are open 24/7. At least some are. I've been there in the wee hours and, judging by the variety of late night owls, it's definitely one of the more interesting spots to see people. Ladies and gentlemen of the night seem oddly different when they are plucking fruit from bins at 3 a.m.
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I'm new here too. The only open-all-night's I know of, so far are the Super Walmarts.
Hope the link below works for you; it's a list of Phoenix Walmarts in general. You probably know, it's mainly the "Super" ones that have a real grocery department. I promise I'm not one of their minions, just a person like you who's gotta eat. :D
